I know Paul van Dyk uses Ableton Live while performing and he started out back in the day on vinyl. He does a lot of neat stuff on it. Nothing crazy, but things like extending buildups and break downs, mixing acapellas, and playing chords over songs.
This video shows what he does.
http://www.youtube.com/watch?v=P1zRiRnen5M
It's cool what he's got going on. Almost like the old school roland drum machines
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